Isaac Scientific Publishing

Journal of Advances in Nanomaterials

Ferrites Nanoflowers for Dye Removal Applications

Download PDF (1001.6 KB) PP. 49 - 56 Pub. Date: December 20, 2016

DOI: 10.22606/jan.2016.12001

Author(s)

  • E.Girgis
    Solid State Physics Department, National Research Centre, 12622 El Buhouth St., Dokki, Cairo, Egypt
  • C. Tharwat*
    Solid State Physics Department, National Research Centre, 12622 El Buhouth St., Dokki, Cairo, Egypt
  • D. Adel
    Solid State Physics Department, National Research Centre, 12622 El Buhouth St., Dokki, Cairo, Egypt

Abstract

Ferrites nanostructures have been prepared with flower-like shape, as novel cost effective dye removal agent to be used in water purification. CoFe2O4, and MnFe2O4 has been prepared via ethylene glycol (EG) mediated self-assembly method. The morphological properties of the as-synthesized nano-flower were investigated using transmission electron microscopy (TEM), and selected area electron diffraction (SEAD). Factors influenced shape of nano-flower, such as time, temperature, pH, and urea concentration has been studied. For water purification applications, it is clear that the as-prepared ferrites nano-flowers represent an excellent efficiency to remove polar red 390 dyes from water with efficiency with 46, and 96% for both of CoFe2O4, and MnFe2O4, respectively.

Keywords

Ferrite nanoflower, urea, dye removal, polar red 390 dye, waste water treatment.

References

[1] HOU Xiang-yu, FENG Jing, LIU Xiao-han, and ZHANG Mi-lin, "Comparable Studies of Adsorption and Magnetic Properties of Ferrite MnFe2O4 Nanoparticles, Porous Bulks and Nanowires", CHEM. RES. CHINESE UNIVERSITIES (2011), 27(4), p.p.543—546.

[2] L. Q. Mai, Y. H. Gu, C. H. Han, B. Hu, W. Chen, P. C. Zhang, L. Xu, W. L. Guo, Y. Dai,"Orientated Langmuir-Blodgett Assembly of VO2 Nanowires", Nano Letters, 92 (2009) pp. 826 - 830.

[3] Cao F, Shi WD, Zhao LJ, Song SY, Yang JH, Lei YQ, Zhang HJ. "Hydrothermal synthesis and high photocatalytic activity of 3D wurtzite ZnSe hierarchical nanostructures", J Phys Chem C.(2008);112: p.p. 17095–17101.

[4] J. L. Zhang, Y. Wang, H. Ji, Y. G. Wei, N. Z. Wu, B. J. Zuo, Q. L.Wang, J. Catal. "Magnetic nanocomposite catalysts with high activity and selectivity for selective hydrogenation of ortho-chloronitrobenzene",(2005), 229, p.p. 114-118.

[5] O. Shekhah, W. Ranke, A. Schule, G. Kolios, R. Schlogl, "Styrene synthesis : high conversion over unpromoted iron oxide catalysts under practical working conditions" (2003) , Angew. Chem. Int. Ed., 42, p.p. 5760-5763.

[6] E. Girgis, D. Adel, C. Tharwat, O. Attallah and K.V. Rao, "Cobalt ferrite nanotubes and porous nanorods for dye removal", Advances in Nano Research, Vol. 3, No. 2 (2015) p.p.111-121 .

[7] P. Li, D.E. Miser, S. Rabiei, R.T. Yadav, M.R. Hajaligol , "The removal of carbon monoxide by iron oxide nanoparticles", Appl. Catal., B – Environ., 43 (2003), pp. 151–162.

[8] K. Woo, H. J. Lee, J. P. Ahn, Y. S. Park, "Sol–gel mediated synthesis of Fe2O3 nanorods", (2003), Adv. Mater., 15, p.p. 1761-1764.

[9] X. G. Wen, S. H. Wang, Y. Ding, Z. L. Wang, S. H. Yang, "controlled growth of large-area, uniform, vertically aligned arrays of alpha-Fe2O3 nanobelts and nanowires" (2005), J. Phys.Chem. B, 109, p.p. 215-220.

[10] C. J. Jia, L. D. Sun, Z. G. Yan, L. P. You, F. Luo, X. D. Han, Y. C.Pang, Z. Zhang, C. H. Yan, "Single-crystalline iron oxide nanotubes", (2005) ,Angew. Chem. Int. Ed., 44, p.p. 4328-4333.

[11] YW Zhu, T Yu, CH Sow, YJ Liu, ATS Wee, XJ Xu, CT Lim, and JTL Thong, "Efficient field emission from alpha-Fe2O3 nanoflakes on an atomic force microscope tip",(2005) Applied Physics Letters, 87, 23103,p.p. 1-3.

[12] Sugimoto, M., The past, present and future of ferrites. J. Am. Ceram. Soc., (1999), 82, p.p. 269–280.

[13] A.K. Giri, E.M. Kirkpatrick, P. Moongkhamklang, S.A. Majetich and V. G. Harris, "Photomagnetism and structure in cobalt ferrite nanoparticles ,(2002), Appl. Phys. Lett. 80, p.p. 2341.

[14] T. Mathew, S. Shylesh, B.M. Devassy, M. Vijayaraj, C.V.V.Satyanarayana, B.S. Rao, C.S. Gopinath," Selective production of orthoalkyl phenols on Cu 0.5 Co 0.5 Fe 2 O 4: a study of catalysis and characterization" (2004) , Appl.Catal. A-Gen. 273, p.p.35-45.

[15] G.V.M. Jacintho, A.G. Brolo, P. Corio, P.A.Z. Suarez, J.C. Rubim," Structural investigation of MFe2O4 (M= Fe, Co) magnetic fluids", (2009) , J. Phys. Chem. C 113, p.p. 7684-7691.

[16] S. Bhattacharyya, J.P. Salvetat, R. Fleurier, A. Husmann, T. Cacciaguerra, M.L. Saboungi," One step synthesis of highly crystalline and high coercive cobalt-ferrite nanocrystals", (2005) ,Chem. Commun. 38, p.p. 4818-48120.

[17] Espantaleon, A.G. Nieto, J.A. Fernandez, M. Marsal," “Use of Activated Clays in the Removal of Dyes and Surfactants from Tannery Waste Waters” (2003), A. Appl Clay Sci. 24:p.p. 105-110.

[18] Khraisheh, M.A.M. & Alg-Houti," Enhanced dye adsorption by micro emulsion-modified calcined diatomite (μE-CD) Adsorption", (2005) , M.S. Adsorption. 11 p.p. 547-549.

[19] Liang-Shu Zhong, Jin-Song Hu, Han-Pu Liang, An-Min Cao, Wei-Guo Song, and Li-Jun Wan," Self-assembled 3D flowerlike nanostructures of iron oxide from ferric chloride and their applications in water treatment", (2006), Adv. Mater., 18, p.p. 2426–2431.